Science
Reduction: sulfur compounds and struck-match aromas
Low-oxygen conditions can leave volatile sulfur compounds in a wine — some transient and prized, some genuinely faulty.
The short answer
Reduction refers to sulfur-containing compounds formed under low-oxygen conditions, principally by yeast under stress. At low concentrations some of them read as struck match or flint and are actively sought; at higher concentrations they read as rotten egg, drains or burnt rubber and are a fault.
Overview
Reduction became far more visible as a topic when screwcaps became widespread, since a low-transmission closure leaves the wine less opportunity to resolve it in bottle.
The vocabulary is unhelpfully overloaded: "reductive winemaking" is a deliberate low-oxygen technique used to preserve aromatics, while "a reduced wine" is one showing an off-aroma. The two are related but not the same.
How it works
The mechanism, at the scope it has actually been established.
Hydrogen sulfide is produced by yeast, particularly when nitrogen nutrition is inadequate. It has an extremely low sensory threshold and smells of rotten eggs.
Hydrogen sulfide can react further to form mercaptans (thiols such as methanethiol and ethanethiol) and disulfides. These have their own characters — cooked cabbage, drains, rubber — and are considerably harder to remove.
The distinction matters practically: hydrogen sulfide often blows off with aeration, while the heavier compounds frequently do not, which is why decanting sometimes fixes the problem and sometimes does not.
At very low concentrations, some sulfur compounds contribute characters many tasters value — the flinty, struck-match note associated with some fine white Burgundy and its imitators. Whether a given example is a fault or a feature is a judgement about concentration and about style.
Copper binds sulfides and has long been used to treat them, though it carries its own consequences for the wine’s later development.
Why it matters in the glass
For a drinker, the practical upshot is worth knowing: a wine that smells of struck match or drains on opening may well clear with vigorous decanting, and it is worth trying before writing the bottle off.
It also explains why some producers deliberately choose closures with slightly higher oxygen transmission for wines they know run reductive.
What people get wrong
1 widely repeated claim this page corrects.
Compounds named on this page
Where a compound comes from is chemistry; what it smells like is perception. These are kept apart deliberately.
- Hydrogen sulfide
- Produced by stressed yeast; the rotten-egg end of reduction. Associated with rotten egg, drains. Caution: Often blows off with aeration. The heavier mercaptans it can react to form generally do not, which is why decanting sometimes helps and sometimes does not.
- Volatile thiols
- Sulfur compounds released by yeast from odourless grape precursors. Associated with passionfruit, grapefruit, box hedge, blackcurrant bud. Caution: The same word covers compounds that are valued at low concentration and treated as reduction faults at higher ones. Context and quantity decide which is which.
Whether a given struck-match character is a fault or a feature is genuinely contested, including among winemakers. The compounds are measurable; the threshold of acceptability is a matter of style and of the individual taster.
Sources
Sources consulted
- The Australian Wine Research Institute — AWRI
- Wine flavours, faults and taints — The Australian Wine Research Institute
- Longitudinal studies comparing wine closures — Peer-reviewed oenological literature
More in wine science
Science
Acidity: the acids in wine and what each does
Tartaric, malic, lactic, citric and acetic acid — where they come from, how they differ, and why pH and total acidity are not the same measurement.
Science
Cool climate and warm climate
The single most useful distinction in wine — what it actually changes in the grape, and where the shorthand breaks down.
Science
Minerality: what the evidence actually shows
A word almost every taster uses, no agreed chemical definition, and no demonstrated route from vineyard rock to matching flavour.